High-Quality MIL-101(Al) Powder Metal Organic Frameworks (MOFs) Service, Supplier

MIL-101(Al) is built from commercially available linkers terephthalate linkers. The SBUs are carboxylate bridged trimeric μ3-O centred aluminium clusters, having C3v symmetry and the general formula Al3(μ3-O)(O2CR)6X3.

Product Description

Product Specifications

Product Name MIL-101 (Al)
Particle size 0.1~0.2μm
Specific surface area ≥1000㎡/g
Pore size 0.4~0.6 mm

Product Overview & Structure

MIL-101(Al), a Metal Organic Framework (MOF), is renowned for its exceptional properties that make it an ideal candidate for a variety of applications, including adsorption, gas storage, separation, and catalysis. Developed at the Lavoisier Institute in France, MIL-101(Al) is composed of terephthalate linkers and trimeric μ3-O centered aluminium clusters, which give it a unique structure and high symmetry.

The framework of MIL-101(Al) is characterized by its mtn topology, akin to the zeolite material ZSM-39. This topology results in a structure with two distinct interconnected mesoporous cages, measuring 27 Å and 34 Å respectively. These large cages are accessible through microporous windows that are hexagonal and pentagonal in shape. The spacious cavities and windows endow MIL-101(Al) with a high potential for gas storage and separation processes, where the size and shape of the pores can be critical for selective adsorption.

One of the key advantages of MIL-101(Al) is its robustness, which is attributed to the strong bonds formed between the aluminium clusters and the carboxylate linkers. This robustness, coupled with the low toxicity of the aluminium-based MOFs, makes them suitable for applications in catalysis, where they can serve as stable and durable catalysts.

KAR-F40 MIL-101(Al)

Key Applications & Capabilities

In addition to gas-related applications, MIL-101(Al) has been explored for its potential in the removal of species from solutions, capitalizing on its large surface area and porosity to effectively capture and sequester contaminants. The material's high specific surface area of over 1000 ㎡/g and its particle size ranging from 100 to 1000 nm further enhance its performance in these applications.

The versatility of MIL-101(Al) extends to the realm of drug delivery, where its porous structure can be utilized for the controlled release of pharmaceutical agents. The ability to tailor the pore size and surface chemistry of MOFs like MIL-101(Al) offers opportunities to design materials that can interact specifically with drug molecules, potentially improving the efficacy and safety of drug delivery systems.

MIL-101(Al) is a multifaceted MOF with a broad spectrum of applications, from environmental remediation to advanced catalysis and drug delivery. Its unique structural features, combined with its robustness and low toxicity, position it as a promising material for future technological advancements and sustainable solutions across various industries.

Frequently Asked Questions (FAQ)

Q What is MIL-101(Al) and how is it structured?

MIL-101(Al) is a Metal-Organic Framework (MOF) composed of terephthalate linkers and trimeric μ3-O centered aluminium clusters. It features an mtn topology with two interconnected mesoporous cages (27 Å and 34 Å) accessible via hexagonal and pentagonal windows.

Q What are the primary specifications of MIL-101(Al)?

MIL-101(Al) features a high specific surface area of ≥1000 ㎡/g, particle size ranging from 0.1 to 0.2 μm (100–1000 nm), and pore size of 0.4~0.6 mm.

Q What makes MIL-101(Al) suitable for catalysis applications?

Its strong chemical bonds between aluminium clusters and carboxylate linkers provide exceptional structural robustness, while the inherent low toxicity of aluminium-based MOFs makes it a durable and stable catalyst.

Q How is MIL-101(Al) used in environmental remediation?

Thanks to its spacious cavities, high porosity, and large surface area, MIL-101(Al) is highly efficient in capturing, sequestering contaminants, and removing specific species from aqueous solutions.

Q Can MIL-101(Al) be utilized in medical or drug delivery systems?

Yes, the customizable pore size and surface chemistry allow MIL-101(Al) to carry and release pharmaceutical agents in a controlled manner, offering improved efficacy and safety for targeted drug delivery systems.

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